酰基

Multi tool use

一般醯基(藍色),醯基離子(頂部中央),醯基自由基(右上),酮(左上),醛(左下),酯(底部中央),醯胺(右下)。 (R1,R2,R3:有機取代基或氫)。
酰基[註 1](英语:acyl group)是指從含氧酸,包括無機酸中除去一個或多個羥基基團的衍生的官能團。它包含一個強制性羰基和烷基。在有機化學中,酰基(IUPAC名:鏈烷酰基)通常是衍生自羧酸。因此,它具有結構式RCO-,其中R代表被附著到CO基用單鍵的烷基。雖然稱呼幾乎總是應用於有機化合物,但酰基原則上可以是來自於其它類型的酸如磺酸,膦酸。在最常見的安排,酰基連接到一個更大的分子片段,在這種情況下,碳和氧原子通過雙鍵相連。
酰基指的是有机或无机含氧酸去掉羟基后剩下的一价原子团,通式为R-M(O)-。酰基与卤素原子、烷氧基、氨基或取代氨基及酰氧基结合可以分别获得酰卤、酯、酰胺和酸酐。[1]
通常酰基中的M原子都为碳,但硫、磷、氙等原子也可以形成类似的酰基化合物,如四氟一氧化氙、硫酰氯、氯化亚砜。此类酰卤一般称为卤氧化物。
参见
腳註
註釋
^ (英文)國際純粹與應用化學聯合會."Acyl groups".《化学术语总目录》在线版.
外部連結
維基共享資源中与酰基相關的分類
有机官能团
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碳氢化合物 |
- 烷烃
烷基
- 累积二烯烃
烯烃
- 炔烃
- 苄基
- 卡宾
- 亚甲基
- 次甲基
- 苯基
苯 · 卤代烷
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碳氢氧化合物 |
官能团中有一个氧 |
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官能团中有两个氧 |
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官能团中有三个氧 |
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除碳氢氧以外 只有一种元素 |
氮 |
- 胺
- 偶氮化物
- 氰酸酯
- 腈
- 異腈
- 肟
- 尿素
- 腙
- 酰胺
- 酰亚胺
- 亚胺
- 异氰酸酯
- 硝基化合物
- 亚硝基化合物
- 吡啶
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磷 |
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硫 |
- 二硫化物
- 砜
- 磺酸
- 亚砜
- 硫醚
- 硫醇
- 硫酯
- 磺酸
- 亚磺酸
- 次磺酸
- 硫代羧酸
- 雙硫鍵
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硒 |
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碲 |
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其他 |
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另见:化学分类, 化学命名法(无机物, 有机物) |
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